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Urinary biomarker investigation in children with Fabry disease using tandem mass spectrometry.
[fabry disease]
Fabry
disease
is
an
X-
linked
lysosomal
storage
disorder
affecting
both
males
and
females
with
tremendous
genotypic
/
phenotypic
variability
.
Concentrations
of
globotriaosylceramide
(
Gb
3
)
,
globotriaosylsphingosine
(
lyso-
Gb
3
)
/
related
analogues
were
investigated
in
pediatric
and
adult
Fabry
cohorts
.
The
aims
of
this
study
were
to
transfer
and
validate
an
HPLC-
MS
/
MS
methodology
on
a
UPLC-
MS
/
MS
new
generation
platform
,
using
an
HPLC
column
,
for
urine
analysis
of
treated
and
untreated
pediatric
and
adult
Fabry
patients
,
to
establish
correlations
between
the
excretion
of
Fabry
biomarkers
with
gender
,
treatment
,
types
of
mutations
,
and
to
evaluate
the
biomarker
reliability
for
early
detection
of
pediatric
Fabry
patients
.
A
UPLC-
MS
/
MS
was
used
for
biomarker
analysis
.
Reference
values
are
presented
for
all
biomarkers
.
Results
show
that
gender
strongly
influences
the
excretion
of
each
biomarker
in
the
pediatric
Fabry
cohort
,
with
females
having
lower
urinary
levels
of
all
biomarkers
.
Urinary
distribution
of
lyso-
Gb
3
/
related
analogues
in
treated
Fabry
males
was
similar
to
the
untreated
and
treated
Fabry
female
groups
in
both
children
and
adult
cohorts
.
Children
with
the
late-onset
p
.
N
215
S
mutation
had
normal
urinary
levels
of
Gb
3
,
and
lyso-
Gb
3
but
abnormal
levels
of
related
analogues
.
In
this
study
,
Fabry
males
and
most
Fabry
females
would
have
been
diagnosed
using
the
urinary
lyso-
Gb
3
/
related
analogue
profile
.
Diseases
Validation
Diseases presenting
"urinary distribution"
symptom
fabry disease
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